Poly(vinyl acetate) was produced in a controlled manner using RAFT chemistry in a miniemulsion system. Homogeneous nucleation of the vinyl acetate monomer was suppressed through the use of an oil soluble initiator, 2,2′azo-bis(isobutyronitrile). The miniemulsion polymerizations exhibited lower reaction rates than a bulk polymerization.
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Russum et al. (2005) studied this question.
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