A variety of 2‐deoxy‐1‐O‐diphenoxylphosphoryl‐hexopyranoses were generated in situ by a radical 2→1 migration of the phosphate group. The structures of the reactive rearrangement products were fully elucidated by NMR spectroscopy. Rate constants for this new rearrangement were determined fro a variety of substrates.
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KOCH et al. (1993) studied this question.
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