Experimental study demonstrates self-assembly of rigid fluorescent supramolecular nanowires via multiple hydrogen bonds, highlighting potential applications in optoelectronic devices.
Supramolecular polymeric nanowires 1(n) constructed by a 3D shape-persistent hexaacid 1 through multiple hydrogen bonding interactions was developed. Single molecular nanoires were also obtained from its highly dilute solution.Hexaacid 1 containing pi-conjugated chromophores successfully self-assembled to afford these nanofibers with high solid quantum efficiency (22%), which provides us a pathway to fabricate optoelectronic devices using these highly fluorescent nanofibers.
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Luo et al. (2009) studied this question.
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