Comparative rheological analysis reveals colloid-like mechanical relaxation in functionalized dendrimer melts, suggesting internal densification restricts branch penetration.
, classical dendrimers with regular branching) do not show such a region. The comparative analysis of FD and CSD suggests that the internal densification due to functionalization prevents the penetration of branches and causes FD to behave like colloidal particles in a crowded environment. Since CSD have no special interactions, we expect that this effect will be common for other dendrimer macromolecules.
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Sheveleva et al. (2022) studied this question.
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