The widths of the J=1 to 2 transition of OCS broadened by collisions with OCS and with CHF 3 and the J=0 to 1 transition CHF 3 broadened by collisions with CHF 3 and with OCS have been measured by a digital fitting of the recorded line shape to the theoretical line shape function. Present theory of rotation energy transfer accurately predicts the width of the self-broadened CHF 3 line and the two foreign gas broadening cases, but there is a small but apparently real discrepancy in the case of the OCS self-broadening.
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Olson et al. (1973) studied this question.
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