Abstract 3,3‐Dimethylbutanol‐2 (3,3‐DMB‐ol‐2) and 2,3‐dimethylbutanol‐2 (2,3‐DMB‐ol‐2) have been decomposed in comparative‐rate single‐pulse shock‐tube experiments. The mechanisms of the decompositions are equation image The rate expressions are They lead to D(iC3H7H) – D((CH3)2(OH) CH) = 8.3 kJ and D(C2H5H) – D(CH3(OH) CHH) = 24.2 kJ. These data, in conjunction with reasonable assumptions, give and equation image The rate expressions for the decomposition of 2,3‐DMB‐1 and 3,3‐DMB‐1 are and
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Wing Tsang (1976) studied this question.
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