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The topic discussed in this article is the synthesis of cationic complexes of plati-num(I1) containing η2−olefins, their reaction with nucleophiles, and the cleavage, under acidic conditions, of the platinum-carbon bond of the addition productsobtained therefrom. Some general features related to the electrotl distribution and bonding, the structural and conformational preferences, the reaction mechanisms and reactivity are discussed.
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Maresca et al. (1994) studied this question.
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