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The reaction between Pd2(dba)3·CHCl3 with PPh2CH2PPh2C(H)COMe results in the formation of Pd(PPh2CHPPh2C(H)COMe)2 (1) in good yield. This complex has been characterized by IR and 1H and 31P{1H} NMR spectroscopy and by X-ray diffraction methods. On the other hand, the reactin of Pd2(dba)3·CHCl3 with [PPh2CH2PPh2CH2COMe]ClO4 yields [Pd(PPh2CH2PPh2C(H)COMe)2](ClO4)2 (2). The interconversion between 1 and 2 is described.
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Falvello et al. (2000) studied this question.
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