A Carbon Nitride/Fe Quaterpyridine Catalytic System for Photostimulated CO2-to-CO Conversion with Visible Light

Efficient and selective photostimulated CO 2 -to-CO reduction by a photocatalytic system consisting of an iron-complex catalyst and a mesoporous graphitic carbon nitride (mpg-C 3 N 4 ) redox photosensitizer is reported for the first time. Irradiation in the visible region (λ ≥ 400 nm) of an CH 3 CN/triethanolamine (4:1, v/v) solution containing [Fe(qpy)(H 2 O) 2 ] 2+ (qpy = 2,2′:6′,2′′:6′′,2′′-quaterpyridine) and mpg-C 3 N 4 resulted in CO evolution with 97% selectivity, a turnover number of 155, and an apparent quantum yield of ca. 4.2%. This hybrid catalytic system, comprising only earth abundant elements, opens new perspectives for solar fuels production using CO 2 as a renewable feedstock.