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O and DMS, monomeric in THF-the degree of aggregation of dimethylcuprates depends on the solvent [Eq. (a)]. The Cu-Cu distance of 2.82 Å was determined by EXAFS for a dimethylcuprate reagent derived from cuprous halide. In contrast, with cyanide as the counterion, no dimers are formed.
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Huang et al. (1998) studied this question.
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