Ion fluctuations and intermembrane interactions in the aqueous dispersions of a dialkylchain cationic surfactant studied using dielectric relaxation spectroscopy and small- and wide-angle X-ray scattering

A dialkylchain cationic surfactant forms the so-called α-gel in water showing virtually no fluidity, which is transformed into a highly fluidic dispersion upon addition of a small amount of salt. This intriguing phenomenon is utilized in household industries. However, the underlying mechanisms remain unclear. Here, we use dielectric relaxation spectroscopy (DRS) and simultaneous small- and wide-angle X-ray scattering (SWAXS) to shed light on this issue. We find that an excess amount of CaCl