A highly effective method for preparation of a variety of sterically hindered chiral binaphthol derivatives has been described which involves the intramolecular 1,3-rearrangement of bis(trialkylsilyl ether) of chiral 3,3′-dibromo-1,1′-bi-2-naphthol with t-BuLi.
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Maruoka et al. (1988) studied this question.
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