Extremely air- and moisture-stable seven-coordinate BiV complexes 1 are obtained readily from di(acetato)tri(aryl)bismuth(v) and tropolone derivatives. The Bi atom in 1 resides in a distorted pentagonal-bipyramidal environment. Thus, stable BiV complexes are now available for biological and medicinal activity studies.
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Dittes et al. (1996) studied this question.
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