Ab initio calculations of the geometry and electronic structure of point defects in ferroelectrics with a perovskite structure

Ab initio calculations of the optimized geometry and the electronic structure of lattice defects in incipient perovskite ferroelectrics SrTiO3 and KTaO3 are performed in the framework of the density functional theory. The results are presented for the Li+ impurity ion at the A site in the KTaO3 and SrTiO3 ferroelectrics; the Mn2+, Cd2+, Ca2+, Mg2+, and Zn2+ ions at the A site and the Mn4+ and Mg2+ ions at the B site in the SrTiO3 compound; and the MN Ti 2+ -V O and Mg Ti 2+ -V O complexes in the SrTiO3 ferroelectric. The results are obtained by the cluster method with allowance made for the structural relaxation initiated by the defect and, for nonisovalent substitutional impurities, with due regard for the charge and spin states of the defect. It is established that the Ca Sr 2+ , Cd Sr 2+ , Mn Ti 4+ , and Mg Ti 2+ ions have a stable central position, whereas the Li K + ion in the KTaO3 compound and the Li Sr + , Mn Sr 2+ , and Zn Sr 2+ defects in the SrTiO3 ferroelectric are off-center ions. The shape of the multiminimum adiabatic potential and the parameters of dielectric relaxators (activation barrier, dipole moment) for polar defects are obtained. The electronic impurity levels are determined for the Li Sr + and Mg Ti 2+ neutral defects.