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Urey—Bradley force constants of methanol have been calculated by a least-squares technique using vibrational-frequency data from CH3OH, CH3OD, CD3OH, and CD3OD. The results show that the vibrational assignment recently proposed by Margottin—Marclou is consistent with the Urey—Bradley field, whereas that of Falk and Whalley is not.
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Zerbi et al. (1963) studied this question.
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