February 3, 1995Angewandte Chemie International Edition in English

Formation of an Alkylperoxoiron( III ) Complex during Oxidations Catalyzed by μ‐Oxodiiron( III ) Complexes

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Abstract

UV/Vis, resonance Raman, and EPR spectroscopy served in characterizing the alkylperoxoiron(III) complex 2, an intermediate in the oxidation of alcohols R'OH with alkyl hydroperoxides ROOH catalyzed by μ-oxo complex 1. The results discussed may provide insight for studies of monooxygenases.

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Ménage et al. (1995) studied this question.

synapsesocial.com/papers/6a8bd120b676b7d1a2fb7e87 https://doi.org/10.1002/anie.199502031

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Formation of an Alkylperoxoiron( III ) Complex during Oxidations Catalyzed by μ‐Oxodiiron( III ) Complexes

Abstract

Discussion

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Formation of an Alkylperoxoiron( III ) Complex during Oxidations Catalyzed by μ‐Oxodiiron( III ) Complexes

Abstract

Discussion

Cite This Study

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