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July 5, 2008Angewandte Chemie

Silver‐Catalyzed Transmetalation between Chlorosilanes and Aryl and Alkenyl Grignard Reagents for the Synthesis of Tetraorganosilanes

Kei Murakami Koji Hirano Hideki Yorimitsu Koichiro Oshima

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Abstract

Silberstreif: Nucleophile Substitutionen von Chlorsilanen mit Aryl-Grignard-Reagentien führen unter Silberkatalyse zu Tetraorganosilanen (siehe Schema). Die Umsetzungen verlaufen wahrscheinlich über in situ erzeugte Diarylargentat-Reagentien.

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Murakami et al. (2008) studied this question.

synapsesocial.com/papers/6a8bf37ee066a6a97ec460ec https://doi.org/10.1002/ange.200801949

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