A spectroscopic study of an orange-red glow from the products of electrical discharge in chlorine has resulted in an identification of the emitter as Cl2(A3II0u+). A kinetic study has provided evidence for the formation of excited molecules in this state by the preassociation of 2P3/2 chlorine atoms. Several detailed mechanisms for the reaction are discussed.
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Bader et al. (1964) studied this question.
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