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January 1, 1969Journal of the Chemical Society A Inorganic Physical Theoretical

Gas-phase Raman spectroscopy of trigonal bipyramidal pentachlorides and pentabromides

I. R. Beattie Geoffrey A. Ozin

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Abstract

The Raman spectra of PCl5, SbCl5, NbCl5, TaCl5, MoCl5, NbBr5, and TaBr5 in the gas phase have been recorded. In all cases the data is consistent with the presence of five-co-ordinate trigonal bipyramidal species. The Raman spectra of gaseous PCl5, SbCl5, and MoCl5, show intersting temperature-dependent effects.

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Beattie et al. (1969) studied this question.

synapsesocial.com/papers/6a8c350752e1a91077e99913 https://doi.org/10.1039/j19690001691

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