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A novel palladium‐catalyzed CH oxidation of isoquinoline N ‐oxides has been developed for regioselectively synthesizing substituted isoquinolines. The method represents the first example of using dialkyl sulfoxides as the alkyl sources for the construction of 1‐alkylated isoquinolines. Moreover, the regioselective halogenation of isoquinoline N ‐oxides is also successful using dihalo sulfoxides as the halide sources.
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Yao et al. (2012) studied this question.
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