Measurement of the universal gas-constant R using a spherical acoustic resonator

We report a new determination of the Universal Gas Constant R: (8.314471 0.OOOOI4)J.mol-1 K-1 The uncertainty in the new value is 1.7 ppm (standard error), a factor of 5 smaller than the uncertainty in the best previous value. The gas constant was determined from measurements of the speed of sound in argon as a function of pressure at the temperature of the triple point of water. The speed of sound was measured with a spherical resonator whose volume was determined by weighing the mercury required to fill it at the tem-perature of the tri~le point. The molar mass of the argon was determined by comparing the speed of sound in it to the speed of sound in a standard sample of argon of accurately known chemical and isotoptic composition.