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The synthesis of a new type of polar membrane having a low glass-transition temperature is described. It is obtained by room-temperature crosslinking between two cyanopropylsiloxane copolymers containing SiCHCH2 and SiH reactive groups. Conventional ionophores and electrolytes may be molecularly dissolved in the copolymers. The crosslinked membrane is used as a supporting matrix in ion-selective electrode devices. The best results are obtained when benzo-15-crown-ether-5 is employed as ionophore.
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Soulié et al. (1992) studied this question.
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