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Nine phenoxarsine derivatives with arsenic in the trivalent state and the pentavalent state are synthesized and studied by mass spectrometry. Their characteristic fragmentation modes and the fragment ions with common structures are discussed. Phenoxarsinic acids are found to be unstable in the gaseous phase at the temperatures studied and tend to form their corresponding anhydrides.
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Tou et al. (1970) studied this question.
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