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[reaction, structure: see text] Pd-catalyzed asymmetric allylic alkylation of dienyl acetates 1 and amination of allyl acetates 2 provides the corresponding chiral products in high regio- and enantioselectivities using 1,1'-P,N-ferrocenes L1a and L2d as ligands, respectively.
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Zheng et al. (2005) studied this question.
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