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All articles of this category A series of P , N -ligands containing a chiral oxazoline ring and a chiral bis( N -tosylamino)phosphine group derived from a 1,2-diamine or a chiral cyclic phosphite group derived from TADDOL has been prepared. These compounds proved to be efficient ligands for enantiocontrol of palladium-catalyzed allylic alkylations and iridium-catalyzed hydrogenations of olefins. asymmetric catalysis - chiral P , N -ligands - allylic alkylation - Ir-catalyzed hydrogenation
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Hilgraf et al. (1999) studied this question.
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