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Chiral diphenylthiophosphoramide L2 prepared from diphenylthiophosphinic chloride and (R)‐(+)‐N‐ethyl‐1,1′‐binaphthyl‐2,2′‐diamine 2 was used as a catalytic chiral ligand in the silver(I)‐catalyzed enantioselective allylation reaction of arylaldehydes with allyltributyltin to furnish high ee (up to 98%) of the homoallylic alcohols. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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Wang et al. (2003) studied this question.
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