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A sign of topological order in a gapped one-dimensional quantum chain is the existence of edge zero modes. These occur in the Z 2-invariant Ising/Majorana chain, where they can be understood using free-fermion techniques. Here I discuss their presence in spin chains with Z n symmetry, and prove that for appropriate couplings they are exact, even in this strongly interacting system. These modes are naturally expressed in terms of parafermions, generalizations of fermions to the Z n case. I show that parafermionic edge zero modes do not occur in the usual ferromagnetic and antiferromagnetic cases, but rather only when the interactions are chiral, so that spatial-parity and time-reversal symmetries are broken.
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