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A model for species diffusion is presented, with evaporation at a moving free boundary. The resulting problem resembles a one-phase Stefan problem with superheating, but the usual Stefan condition at the moving boundary is replaced by a version which, in the classical setting, would violate conservation of energy. In the fast evaporation limit, however, the problem reduces to a classical nonlinear Stefan problem with negative latent heat.
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Fliert et al. (2000) studied this question.
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