Shock Formation in a Multidimensional Viscoelastic Diffusive System

We examine a model for non-Fickian “sorption overshoot” behavior in diffusive polymer-penetrant systems. The equations of motion proposed by Cohen and White [SIAM J. Appl. Math., 51 (1991), pp. 472–483] are solved for two-dimensional problems using matched asymptotic expansions. The phenomenon of shock formation predicted by the model is examined and contrasted with similar behavior in classical reaction-diffusion systems. Mass uptake curves produced by the model are examined and shown to compare favorably with experimental observations.