The weak-link approach is used to synthesize a four-coordinate CuI complex for the chiral recognition of mandelic acid. The chelation through 2,2′-bipyridine in a reaction that concomitantly breaks weak CuS links and opens the condensed structure into a 27-membered macrocycle switches on the complex so it acts as an enantioselective fluorescent receptor.
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Heo et al. (2005) studied this question.
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