⌘+K

Pulse Explore Communities Researchers Journals

Browser extensionInstagram

Home Communities Explore

January 1, 1966Journal of the Chemical Society B Physical Organic

Electron spin resonance studies of oxidation. Part VIII. Elimination reactions of some hydroxyalkyl radicals

A. L. Buley R. O. C. Norman R. J. Pritchett

View at Publisher

Ask AI

Bookmark

Share

Ask about this paper

Answers are grounded in this paper and cite their sources.

Ask your own question…

Abstract

The electron spin resonance spectra of radicals generated by the one-electron oxidation of some diols and related compounds are described and discussed. Evidence is adduced that radicals of the type HO–Ċ[graphic omited]–C[graphic omited]–X, where X is a good leaving-group, readily undergo elimination to give OC[graphic omited]–Ċ. The spectrum of the radical ·CH2CHO is discussed.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Buley et al. (1966) studied this question.

synapsesocial.com/papers/6a8db470848f50d54b5be69e https://doi.org/10.1039/j29660000849

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 10 related papers. Consider them for comparative context:

1Infrared absorption and isomerism of 3-aminocrotonic esters. Part I. 3-(Alkylamino)crotonic estersJournal of the Chemical Society B Physical Organic · 1971
2Substitution at saturated carbon. Part VIII. Solvent effects on the free energy of trimethylamine, the nitrobenzyl chlorides, and the trimethylamine–nitrobenzyl chloride transition statesJournal of the Chemical Society B Physical Organic · 1971
3Free-radical reductions of arenediazonium ions in aqueous solution. Part I. Toluene-p-diazonium ions reduced with methanolJournal of the Chemical Society B Physical Organic · 1971
4Mechanisms of elimination reactions. Part III. Rate coefficients for elimination from substituted 2-phenylethyl arenesulphonates with potassium in t-butyl alcoholJournal of the Chemical Society B Physical Organic · 1971
5Nuclear magnetic resonance spectra of glycolaldehydeJournal of the Chemical Society B Physical Organic · 1971
6Evidence for S N2(P) mechanism in the phosphorylation of alkaline phosphatase by substratesJournal of the Chemical Society B Physical Organic · 1971
7A theoretical study of the Edward–Lemieux effect (the anomeric effect). The stereochemical requirements of adjacent electron pairs and polar bondsJournal of the Chemical Society B Physical Organic · 1971
8Pressure effects and quantum yields in the photolysis of ethylene and propene at 185 nmJournal of the Chemical Society B Physical Organic · 1971
9Hydrolysis of phosphinic esters: general-base catalysis by imidazoleJournal of the Chemical Society B Physical Organic · 1971
10Aromatic reactivity. Part XLVIII. Hydrogen exchange in the methyl groups of 2-methyl-, 3-methyl-, and 2,3-dimethyl-benzo[b]thiophenJournal of the Chemical Society B Physical Organic · 1971

More from Journal of the Chemical Society B Physical Organic