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The inclusion copolymerization of various vinyl monomer systems was studied in a thiourea and perhydrotriphenylene matrix while that of a disubstituted butadiene system was investigated in canals of thiourea, perhydrotriphenylene, deoxycholic acid and β‐cyclodextrine. The results were compared with those obtained for the corresponding free copolymerization especially with regard to copolymer composition. In all vinyl monomer systems inclusion copolymerization leads to the same copolymer composition as is found in the free process. On the other hand, in case of the diene system, the copolymer composition of the inclusion products is remarkably different from that of the copolymers formed by the free reaction; the former is always nearly ideal statistic independent of the nature of the host. Inclusion homopolymerization can successfully be carried out with monomers where the free radical polymerization is prevented by allylic inhibition.
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Schneider et al. (1986) studied this question.
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