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A liquid membrane Ag+-selective electrode of our construction and a commercial solid membrane Ag+/S2--selective electrode were used for the determination of thiobarbiturates by potentiometrie titration with AgNO3 solution or by direct potentlometry. The potentio-setrio data correlated vd. th IR spectra allowed the elucidation of the reaction mechanism.
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C⊘ofret et al. (1979) studied this question.
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