A ferromagnetic exchange interaction that is not influenced by the distortion of the cubane framework of 1 (see picture; only the O atoms of the EtOH and dbm− ligands are shown) and is mediated by the end-on-coordinated μ3-azide bridges has been detected for the first time. Although the unusual [M4(η1-μ3-N3)4] core is also displayed by a Pt complex, 1 is the first parmagnetic example. (dbmH = dibenzoylmethane).
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Halcrow et al. (1995) studied this question.
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