Radical protection makes a biradical: High-temperature-stable biradicaloids [P(μ-NR)]2 (R=Ter, Hyp) were isolated from [ClP(μ-NR)]2 when mild reducing agents were employed. The bulky substituents prevent dimerization. Ter=2,6-Mes2C6H3, with Mes=2,4,6-Me3C6H2; Hyp=(Me3Si)3Si.
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Beweries et al. (2011) studied this question.
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