January 21, 2004Angewandte Chemie International Edition

Synthesis and Structure of a 1,3‐Diphosphacyclobutadienediide: An Aniomesolytic Fragmentation of a 1,3‐Diphosphetane‐2,4‐diyl in Solution

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Authors

MSM. SebastianCentre National de la Recherche Scientifique MNMartin NiegerUniversity of Helsinki DSDénes SzieberthUniversity of Pannonia

Abstract

Stepwise reduction of the 1,3-diphosphetane-2,4-diyl 1 by alkali metals (Li, K) leads to the 1,3-diphoshacyclobutadiendiide salts 2 by aniomesolytic fragmentation. DFT calculations provide insight into the reaction pathway.

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Sebastian et al. (2004) studied this question.

synapsesocial.com/papers/6ab343337caff4f3d1cb6235 https://doi.org/10.1002/anie.200352746

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Synthesis and Structure of a 1,3‐Diphosphacyclobutadienediide: An Aniomesolytic Fragmentation of a 1,3‐Diphosphetane‐2,4‐diyl in Solution

Abstract

Discussion

Cite This Study

Synthesis and Structure of a 1,3‐Diphosphacyclobutadienediide: An Aniomesolytic Fragmentation of a 1,3‐Diphosphetane‐2,4‐diyl in Solution

Abstract

Discussion

Cite This Study

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