A borylsilane regioselectively adds to 1,2-dienes in the presence of palladium complexes to afford high yields of alkenylboranes having allylsilane moieties, whereas a borylstannane gives a 1 : 2 telomer with 3-methylbuta-1,2-diene due to borylstannylative dimerization.
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Onozawa et al. (1999) studied this question.
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