2-Methyleneaziridine are a good substrate for the catalytic synthesis of cyclopentylidenamines via a [3 + 2] cycloaddition of 1,1-dicyanoalkenes using Bu2SnI2 as an effective catalyst. A C-attack from 2-methyleneaziridine yielded the desired products.
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Takahashi et al. (2014) studied this question.
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