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The main purpose of this paper is to investigate the asymptotic behavior of the reduced probability density, ρp+q+s ({p}, {q}, {s}), of p+q+s molecules when the molecules within each of the three subsets {p}, {q}, and {s}, are close together but there are large separations between the sets of p, q, and s particles. The interest is in the case where p, q, and s are unity or two. One may use the asymptotic long-range correlation function to understand the critical singularity of the thermodynamic quantities at the critical point.
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Teresa Ree Choy (1967) studied this question.
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