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A new defect center that is believed to be the equivalent of the interstitial halide atom is observed in x-rayed pure LiF. It has the form of a negatively charged diatomic halide molecule situated on a single halide site and orientated along a [111] axis. The ESR constants are gₓ=gy=2.0105, gz=2.0017, Tₓ=Ty=19.0 G, and Tz=1005.9 G.
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Chu et al. (1968) studied this question.
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