A Reductive‐Aggregation Route to [Mn12O12(OMe)2(O2CPh)16(H2O)2]2− Single‐Molecule Magnets Related to the [Mn12] Family

Anastasios J. Tasiopoulos; Wolfgang Wernsdorfer; Khalil A. Abboud; George Christou

doi:10.1002/ange.200461551

November 23, 2004Angewandte Chemie

A Reductive‐Aggregation Route to [Mn12O12(OMe)2(O2CPh)16(H2O)2]2− Single‐Molecule Magnets Related to the [Mn12] Family

View at Publisher

Ask AI

Bookmark

Share

Ask about this paper

Answers are grounded in this paper and cite their sources.

Abstract

Eine Jahn-Teller-Isomerie (d. h. eine Jahn-Teller-Verzerrung entlang verschiedener Achsen) erklärt, warum in der Titelverbindung, einem Einzelmolekülmagnet (SMM; siehe Kernstruktur: blau Mn, rot O, grau C), eine schneller und eine langsamer relaxierende Magnetisierung auftritt. Die Verbindung ist eine Strukturvariante der [Mn12]-SMM-Familie und wurde durch reduktive Aggregation von [MnO4]− in einer MeOH/PhCO2H-Mischung erhalten.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Tasiopoulos et al. (2004) studied this question.

synapsesocial.com/papers/6a911eb3691d66ffc0e1b174 https://doi.org/10.1002/ange.200461551

View at Publisher

Ask AI

Bookmark

Share

A Reductive‐Aggregation Route to [Mn12O12(OMe)2(O2CPh)16(H2O)2]2− Single‐Molecule Magnets Related to the [Mn12] Family

Ask about this paper

Abstract

Discussion

Cite This Study

A Reductive‐Aggregation Route to [Mn12O12(OMe)2(O2CPh)16(H2O)2]2− Single‐Molecule Magnets Related to the [Mn12] Family

Ask about this paper

Abstract

Discussion

Cite This Study

Keep reading

Keep reading