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February 16, 1998Applied Physics LettersOpen Access

Determination of surface polarity of c-axis oriented ZnO films by coaxial impact-collision ion scattering spectroscopy

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Authors

TOTsuyoshi OhnishiNational Institute for Materials ScienceAOAkira OhtomoTokyo Institute of TechnologyMKM. KawasakiUniversity of Geneva

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Overview

Spectroscopic analysis reveals oxygen-face termination in c-axis zinc oxide films on sapphire, highlighting preferential growth driven by interface chemistry and sublimation stability.

Key Points

  • To determine the crystallographic surface polarity of c-axis oriented wurtzite-type zinc oxide epitaxial films grown on sapphire substrates.
  • Synthesized zinc oxide epitaxial films on sapphire (α-Al2O3) (0001) substrates via laser molecular beam epitaxy using a zinc oxide ceramic target.
  • Identified top surface termination using coaxial impact-collision ion scattering spectroscopy by directly comparing film spectra with bulk single-crystal reference faces.
  • Spectroscopic data showed that the top surface of the epitaxial film terminates exclusively with the oxygen-polar (0001̄) crystallographic plane.
  • Identified that the preferential [0001̄] growth direction is driven by interfacial chemical interactions with the substrate and enhanced surface stability against thermal sublimation.

Cite This Study

Ohnishi et al. (1998) studied this question.

synapsesocial.com/papers/6a9134e45ec22faf44c64f44https://doi.org/10.1063/1.120905
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