Nucleation Barrier for Volume‐Conserving Shape Changes of Faceted Crystals

This paper considers volume‐conserving shape changes of small faceted particles or cavities; these changes are driven by surface‐energy reduction. If these changes require normal motion of the facets (singular surfaces), and if the perimeter free energy σ p (per unit area) of a nucleus of a new facet layer is comparable to a typical surface free energy (σ∼ 1 J/m 2 ), the energy barrier is prohibitively large for facets larger than a limiting size of approximately a nanometer unless they are intersected by dislocations that provide a source of steps. In the absence of such dislocations, particles that contain these facets are immobilized in their initial shapes. If σ p < σ, the limiting facet size is increased by a factor of approximately σ/σ p .