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We report the (7×{}1) reconstruction of the clean (112{}0) surfaces of the lanthanide elements Ho and Er. For both elements low-energy electron diffraction showed a sharp sixfold symmetric pattern of spots, indicating a collapse of the ideal open surface to a close-packed structure very similar to a (0001) surface. The absence of any diffraction spots from the underlying ideal structure implies that the reconstruction is many layers deep. Angle-resolved ultraviolet photoelectron spectroscopy (ARUPS) data taken from the reconstructed Ho(112{}0)-(7×{}1) surface are found to be virtually indistinguishable from those taken from a Ho(0001) sample---minor discrepancies may be due to differing surface topographies of the samples. The stability of the ARUPS spectra with temperature implies that the Ho(112{}0)-(7×{}1) surface remains reconstructed at temperatures up to 1000 K. By contrast, the spectra from Er(112{}0) change considerably in the temperature range 800--1000 K. It is not yet known whether this is due to a transformation of the reconstructed surface back to its ideal structure or simply a roughening of the surface.
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Barrett et al. (1991) studied this question.
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