Photoelectron spectra from atomic barium were recorded following excitation with synchrotron radiation at selected autoionization resonance energies. The greatly enhanced intensities of peaks arising from certain levels in Ba⁺ elucidate the structures of the autoionizing levels and implicate Auger decay as the dominant mode for their interaction with the continuum. Resonance photoelectron spectroscopy shows promise of wide applicability.
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Rosenberg et al. (1979) studied this question.
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