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Cyclopentadienyl ligands functionalized by quinoline or N, N -dimethylaniline have an ideal and rigid geometry for the formation of half-sandwich compounds. As a result, stable chromium(III) complexes 5 − 8 with intramolecular nitrogen coordination have been obtained. Treatment with MAO leads to highly active, temperature-stable catalysts for the polymerization of ethylene.
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Enders et al. (2001) studied this question.
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