The position of deuterium in the products of the addition of HCL and DCI to exo 5, 6‐d2 norbornene has been determined mass spectrometrically by measuring metastable ion abundances. The results show a stereo‐selective hydrogen atom abstraction when the molecular ion of exo‐2‐norbornyl chloride fragements by loss of a chloroethyl radical.
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Holmes et al. (1971) studied this question.
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