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Dispersed fluorescence spectra for S0 to S1 vibronic transitions in anthracene are computed using the semiempirical QCFF/PI approach plus corrections resulting from fits to experimental spectral intensities. Extensive comparisons are made with the experimental jet spectra. The nature and assignment of low lying levels are clarified within the normal mode picture, whereas higher energy spectra are shown to be considerably broadened by low order anharmonic corrections.
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Grüner et al. (1994) studied this question.
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