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Fourier transmission spectroscopic and laser calorimetric measurements have been used to characterize bulk and surface impurity bands in CVD ZnSe. Temperature dependence studies indicate that, while absorption between 1200 cm-(l) and 1800 cm-(1) is mainly from bulk molecular impurities, surface impurities also contribute and introduce a departure from the expected exponential dependence of multiphonon absorption with frequency above 850 cm-(1).
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Herbert G. Lipson (1977) studied this question.
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