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Experimental study demonstrates the synthesis of a cyclic alkyl amino olefin-stabilized vinyl(silyl)disilene, indicating novel pathways for stabilizing reactive silicon-silicon double bonds.
Herein, we report the synthesis and characterization of a MeCAAO-stabilized disilene (3), which is stable below 263 K. Upon warming to room temperature, it reacts with the by-product BrSi(SiMe3)3, affording the corresponding oxidative product (4). Furthermore, density functional theory (DFT) calculations were performed to obtain deeper insight into the electronic structures of the compounds.
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Gaurav et al. (2026) studied this question.
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